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The pop star, 26, drew cheers when she drove through the gates of the Casa Hogar Elim orphanage in Nuevo Laredo, Mexico, in a white 2007 Chrysler Town and Country eight seat van and handed the keys to Mama Lupita,who runs the home.
Jessica said "I'm so honored and happy to help" as she hugged Mama Lupita
A representative for the star said: "The kids were cheering when she pulled
"What an amazing surprise!" Simpson said, putting her hand on her heart.
Jessica was accompanied by her mother Tina and her manager father Joe.
"The kids were cheering when she pulled up," Simpson's rep tells PEOPLE. "They surrounded the car and were so excited to see her. They kept saying, 'Muchas gracias! Muchas gracias!' A few of them spoke English and said, 'We love you, Jessica!' "
Said Walker: "Dining with boyfriend John Mayer at fabulous Rome ristorante Dal Bolognese... Daddy's Little Girl asked the waiter tossing a salad at their table, 'Do you have Italian dressing?'
The waiter roared with laughter and Jessica turned red as the guy replied: 'My dear, all of our dressings are Italian!' "